Chapter 22: Introduction to Condensed Matter Physics

22.1 Introduction to Condensed Matter Physics

Condensed matter physics is a branch of physics that deals with the study of the properties and behavior of solids, liquids, and other forms of condensed matter. The study of condensed matter is crucial for understanding the fundamental principles governing materials and their applications in various technologies. In this chapter, we will provide an introduction to condensed matter physics, including some of its key concepts and topics.

22.2 Crystal Structure

A crystal is a periodic arrangement of atoms, ions, or molecules in a three-dimensional lattice structure. Crystals are described by unit cells, which are the smallest repeating units of the lattice. There are several types of unit cells, including simple cubic, body-centered cubic, and face-centered cubic. The arrangement of atoms in a crystal can be characterized by the crystal lattice vectors and the basis, which defines the atomic positions within the unit cell.

22.3 Bravais Lattices

Bravais lattices are a set of 14 unique lattice structures that can describe all possible periodic crystal structures. The Bravais lattices are defined by their symmetry and can be categorized into seven crystal systems, such as cubic, tetragonal, and hexagonal. Each crystal system has a distinct set of lattice parameters and crystallographic point groups.

22.4 Reciprocal Lattice

The reciprocal lattice is a mathematical construction used to describe the diffraction properties of a crystal. It is defined as the set of all vectors G such that e^{i\vec{G}\cdot\vec{R}} = 1 for any lattice vector \vec{R}. The reciprocal lattice is useful for understanding the behavior of waves, such as X-rays and electrons, when they interact with a crystal.

22.5 Electronic Band Structure

In a crystal, the electrons are subject to a periodic potential created by the lattice of atomic cores. The electronic states in a solid can be described by energy bands, which are continuous ranges of allowed energy levels. The energy bands are separated by forbidden energy gaps, known as band gaps. The band structure of a material determines many of its properties, such as electrical conductivity, optical absorption, and thermal properties.

Band structure and density of states plots created by VASP first-principles calculations. Condensed Matter physics.
Band structure and density of states plots for diamond, created by VASP using first-principles methods.

22.6 Semiconductors

Semiconductors are materials with a small band gap between their valence band (occupied by electrons) and conduction band (empty states). At room temperature, a small fraction of the electrons can be thermally excited from the valence band to the conduction band, allowing the material to conduct electricity. The electrical properties of semiconductors can be controlled by doping, which involves the intentional introduction of impurities to create additional charge carriers.

Chapter Summary

In this chapter, we introduced the fundamentals of condensed matter physics, including the study of crystal structures, Bravais lattices, and the reciprocal lattice. We also discussed electronic band structures and the properties of semiconductors. Condensed matter physics is a broad field with numerous applications in technology and materials science, and its study is essential for understanding the behavior and properties of various materials.

Continue to Chapter 23: Introduction to Nuclear Physics

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